Ion-Pair Reactivity in Isotopic Exchange Reactions. I. Lithium Chloride in Acetone as Solvent.
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چکیده
منابع مشابه
Are ate complexes true intermediates in lithium-metalloid exchange? Subtle effects of ion-pair structure in lithium-tellurium and lithium-selenium exchange reactions.
The lithium±metalloid exchange reaction is widely used to prepare synthetically valuable organolithium reagents. The full synthetic potential of one of the most important of these reactions, the Li/I exchange, was not realized (e.g., in the synthesis of alkyllithium reagents) until mechanistic studies showed that it was a well-behaved polar process without a significant radical component.[1a,b,...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1969
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.23-1175